If you have already unlocked the Trade Station, and joined an Alliance, you can click on Alliance Aid in the Trading Station. There, you can request and send Items and Resources to Alliance members.
In the Trade Station, click on Alliance Aid. Then you can see equal-order requests made by each Alliance member, as well as requests for specific concrete items. Select the relevant item, and you will have the option to trade it. When you provide assistance to others, your item will be sent to them. You can also request Alliance Aid from Alliance members.
Please note:
1. Alliance Aid does not use up a march slot.
2. Item and Resource Trading within the Alliance Aid is possible only between Alliance members.
3. For Sending Trade requests: There is a limit to the number of requests you can send daily. The Alliance Aid Trade Capacity will increase 100% for Lv.6+ VIP players.
4. Tax: There is no tax in the Alliance Aid.
5. New members of an alliance can use the Alliance Aid immediately.
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Game Guide for Z Day: Hearts of Heroes